Intermediate spin ground state of an isosceles triangular [Mn(II)(3)] complex.
نویسندگان
چکیده
[{Mn(tmeda)}(3){GeSe(3)(OMe)}(2)] (), synthesized by the reaction of [K(4)(H(2)O)(3)][Ge(2)Se(6)] with MnCl(2).4H(2)O in MeOH-tmeda (tmeda = N,N,N',N'-tetramethyl-1,2-diaminoethane), exhibits an isosceles triangular arrangement of Mn(2+) ions that are antiferromagnetically coupled with an S = 3/2 ground state.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 39 شماره
صفحات -
تاریخ انتشار 2009